Issue 15, 2000
From the journal:

Chemical Communications

Synthesis of a stable stibabismuthene; the first compound with an antimony–bismuth double bond

Takahiro Sasamori,a   Nobuhiro Takeda†b  and  Norihiro Tokitoh†*b  

* Corresponding authors

a Department of Chemistry and Physics of Condensed Matter, Graduate School of Science, Kyushu University, Japan

b Institute for Fundamental Research of Organic Chemistry, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, Japan.
E-mail: E-mail: tokitoh@boc.kuicr.kyoto-u.ac.jp

Abstract

The condensation reaction of an overcrowded dihydrostibine with dibromobismuthine using 1,8-diazabicyclo[5.4.0]undec-7-ene as a base afforded the first stable stibabismuthene, the formation of which was evidenced by UV–VIS and Raman spectra and its chemical reactivity.

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Article information

DOI
https://doi.org/10.1039/B001900N
Article type
Communication
Submitted
08 Mar 2000
Accepted
14 Jun 2000
First published
30 Jun 2000

Chem. Commun., 2000, 1353-1354

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Synthesis of a stable stibabismuthene; the first compound with an antimony–bismuth double bond

T. Sasamori, N. Takeda and N. Tokitoh, Chem. Commun., 2000, 1353 DOI: 10.1039/B001900N

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