Issue 14, 2000
From the journal:

Chemical Communications

Pyridine

Arran A. D. Tulloch,a   Andreas A. Danopoulos,*a   Robert P. Tooze,b   Sean M. Cafferkey,a   Sven Kleinhenza  and  Michael B. Hursthouse*a  

* Corresponding authors

a Department of Chemistry, University of Southampton, Highfield, Southampton, UK
E-mail: ad1@soton.ac.uk

b Ineos Acrylics, Wilton, PO Box 90, Middlesbrough, Cleveland, UK

Abstract

The pyridine functionalised N-heterocyclic carbene complexes (C–N)PdMeBr, C–N = 3-R-1-(2-picolyl)imidazolin-2-ylidene, (R = But 1a, R = mes 1b, mes = mesityl) are described; they are excellent catalysts for the Heck arylation; 1b is monomeric with a chelating C–N ligand; the product obtained by interaction of 1a with AgO2CCF3 shows a [Pd(C–N)]4 framework with bridging C–N ligands.

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Article information

DOI
https://doi.org/10.1039/B002645J
Article type
Communication
Submitted
28 Mar 2000
Accepted
26 May 2000
First published
20 Jun 2000

Chem. Commun., 2000, 1247-1248

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Pyridine functionalised N-heterocyclic carbene complexes of palladium

A. A. D. Tulloch, A. A. Danopoulos, R. P. Tooze, S. M. Cafferkey, S. Kleinhenz and M. B. Hursthouse, Chem. Commun., 2000, 1247 DOI: 10.1039/B002645J

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