Palladium catalyzed phosphination of substituted aryl bromides using triarylphosphines as the phosphinating agents has been developed; this method tolerates ketone, aldehyde, ester, nitrile, ether and chloride functional groups.
A general synthesis of aryl phosphines by palladium catalyzed phosphination of aryl bromides using triarylphosphines
F. Y. Kwong and K. S. Chan, Chem. Commun., 2000, 1069 DOI: 10.1039/B002656P
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