Ternary nitrides Fe3Mo3N, Co3Mo3N and Ni2Mo3N, exhibit high catalytic activities in ammonia synthesis; promotion of Co3Mo3N with caesium results in higher activity than that of the commercial multi-promoted iron based catalyst.
Novel class of ammonia synthesis catalysts
C. J. H. Jacobsen, Chem. Commun., 2000, 1057 DOI: 10.1039/B002930K
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