Issue 14, 2000
From the journal:

Chemical Communications

Observations on the transition-metal catalysed oxidation of alkanes in trifluoroacetic acid: urea–hydrogen peroxide/TFA as a convenient method for the oxidation of unactivated C–H bonds

Christopher J. Moodya  and  Jenny L. O’Connella  

a School of Chemistry, University of Exeter, Stocker Road, Exeter, UK
E-mail: c.j.moody@ex.ac.uk

Abstract

Oxidation of cyclohexane in TFA using 30% aqueous H2O2 or urea–H2O2 (UHP) gives cyclohexyl trifluoroacetate in good yield, although the reaction is not accelerated by rhodium or ruthenium catalysts casting doubt on earlier claims on the role of transition-metals in oxidations in TFA.

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Article information

DOI
https://doi.org/10.1039/B003074K
Article type
Communication
Submitted
17 Apr 2000
Accepted
22 May 2000
First published
28 Jun 2000

Chem. Commun., 2000, 1311-1312

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Observations on the transition-metal catalysed oxidation of alkanes in trifluoroacetic acid: urea–hydrogen peroxide/TFA as a convenient method for the oxidation of unactivated C–H bonds

C. J. Moody and J. L. O’Connell, Chem. Commun., 2000, 1311 DOI: 10.1039/B003074K

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