Phosphines containing two N-bound pyrrolidine groups and one alkyl or aryl group are unusually electron rich σ-donor ligands when compared to either tris(N-pyrrolidinyl)phosphine or trialkyl- and triaryl-phosphines.
P–N bond formation as a route to highly electron rich phosphine ligands
M. L. Clarke, D. J. Cole-Hamilton, A. M. Z. Slawin and J. D. Woollins, Chem. Commun., 2000, 2065 DOI: 10.1039/B004893N
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