Regio- and stereo-selectivity in the intramolecular quenching of the excited benzoylthiophene chromophore by tryptophan

Abstract

Laser flash photolysis studies on the photobehaviour of a series of bichromophoric derivatives bearing benzoylthiophene and tryptophan groups have shown that the efficiency of the intramolecular quenching process depends on both the stereochemistry of the chiral centers and the relative ketone versus tryptophan orientation.