Can 4,4′-bipyridine N,N ′-dioxide play the same important role as 4,4′-bipyridine in the construction of metal coordination networks and crystal engineering?

De-Liang Long; Alexander J. Blake; Neil R. Champness; Martin Schröder

doi:10.1039/B006679F

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Can 4,4′-bipyridineN,N ′-dioxide play the same important role as 4,4′-bipyridine in the construction of metal coordination networks and crystal engineering?Electronic supplementary information (ESI) available: molecualr structures and labelling schemes for complexes 1 and 2. See http://www.rsc.org/suppdata/cc/b0/b006679f/

De-Liang Long,^a Alexander J. Blake,^a Neil R. Champness*^a and Martin Schröder*^a

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* Corresponding authors

^a School of Chemistry, The University of Nottingham, University Park, Nottingham, UK
E-mail: neil.champness@nottingham.ac.uk; M.Schroder@nottingham.ac.uk

Abstract

Various binding modes of 4,4′-bipyridine N,N′-dioxide (L) for crystal engineering are demonstrated in the complexes [Zn(MeOH)₂L₃](SiF₆)·3MeOH and [ZnL₆](NO₃)₂, which include examples of M–L coordination bonds, hydrogen-bonding and π–π stacking interactions.

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Article information

DOI: https://doi.org/10.1039/B006679F
Article type: Communication
Submitted: 15 Aug 2000
Accepted: 02 Oct 2000
First published: 07 Nov 2000

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Chem. Commun., 2000, 2273-2274

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Can 4,4′-bipyridine N,N ′-dioxide play the same important role as 4,4′-bipyridine in the construction of metal coordination networks and crystal engineering?

D. Long, A. J. Blake, N. R. Champness and M. Schröder, Chem. Commun., 2000, 2273 DOI: 10.1039/B006679F

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