A series of novel polynuclear mercury(II) diimine complexes with bridging chalcogenolate ligands have been synthesized and characterized and their luminescence and electrochemical properties studied. The crystal structures of [Hg(μ-SC6H4OCH3-p)(bpy)]n[PF6]n and [Hg(μ-SeC6H5)(bpy)]n[PF6]n have also been determined (bpy = 2,2′-bipyridine).
V. Wing-WahYam, Y. Pui and K. Cheung, J. Chem. Soc., Dalton Trans., 2000, 3658 DOI: 10.1039/B005085G
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