Issue 2, 2001
From the journal:

Chemical Communications

Heterobimetallic intermediates in alkene insertion reactions into a Pd–acetyl bondElectronic supplementary information (ESI) available: Experimental. See http://www.rsc.org/suppdata/cc/b0/b007171o/

Pierre Braunstein,a   Jérôme Durand,a   Michael Knorra  and  Carsten Strohmannc  

a Laboratoire de Chimie de Coordination (UMR 7513 CNRS), Institut Le Bel, Université Louis Pasteur, 4 rue Blaise Pascal, Strasbourg, France.
E-mail: braunst@chimie.u-strasbg.fr

b Laboratoire de Materiaux Moléculaires et Interfaces, Faculté des Sciences et Techniques, Université de Franche-Comté, 16 route de Gray, Besançon, France.
E-mail: michael.knorr@univ-fcomte.fr

c Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, Würzburg, Germany

Abstract

The reactivity of diphosphine-bridged heterobimetallic Fe–Pd alkyl complexes was evaluated for the insertion of CO, isonitriles, ethylene, methyl acrylate and norbornadienes and the crystal structures of the precursor alkyl complex, the iminoacyl derivative and the five-membered ring complex resulting from ethylene insertion into the palladium–acyl bond are reported.

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Article information

DOI
https://doi.org/10.1039/B007171O
Article type
Communication
Submitted
05 Sep 2000
Accepted
12 Dec 2000
First published
15 Jan 2001

Chem. Commun., 2001, 211-212

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Heterobimetallic intermediates in alkene insertion reactions into a Pd–acetyl bond

P. Braunstein, J. Durand, M. Knorr and C. Strohmann, Chem. Commun., 2001, 211 DOI: 10.1039/B007171O

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