Issue 3, 2001
From the journal:

Chemical Communications

Nickel-catalysed acylstannylation of 1,2-dienes: synthesis and reactions of α-(acylmethyl)vinylstannanes

Eiji Shirakawa,*a   Yoshiaki Nakaob  and  Tamejiro Hiyama*b  

* Corresponding authors

a Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, Asahidai, Tatsunokuchi, Ishikawa, 923-1292, Japan

b Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan

Abstract

Bis(cycloocta-1,5-diene)nickel was found to be an effective catalyst for the acylstannylation of 1,2-dienes to give a wide variety of α-(acylmethyl)vinylstannanes, which were transformed to variously substituted conjugated and unconjugated enones by carbon–carbon bond forming reactions.

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Article information

DOI
https://doi.org/10.1039/B008190F
Article type
Communication
Submitted
10 Oct 2000
Accepted
26 Oct 2000
First published
23 Jan 2001

Chem. Commun., 2001, 263-264

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Nickel-catalysed acylstannylation of 1,2-dienes: synthesis and reactions of α-(acylmethyl)vinylstannanes

E. Shirakawa, Y. Nakao and T. Hiyama, Chem. Commun., 2001, 263 DOI: 10.1039/B008190F

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