Issue 2, 2001
From the journal:

Chemical Communications

Highly stereoselective addition to alkoxy or hydroxy ketones using an α-stannyl ester–stannous chloride system in a chelation-controlled manner

Makoto Yasuda,a   Keishi Okamoto,a   Toshifumi Sakoa  and  Akio Baba*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
E-mail: baba@ap.chem.eng.osaka-u.ac.jp

Abstract

The reaction of an α-stannyl ester with α-alkoxy or hydroxy ketones in the presence of SnCl2 gave aldol-type products with high selectivity in a chelation-controlled manner.

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Article information

DOI
https://doi.org/10.1039/B008493J
Article type
Communication
Submitted
20 Oct 2000
Accepted
21 Nov 2000
First published
04 Jan 2001

Chem. Commun., 2001, 157-158

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Highly stereoselective addition to alkoxy or hydroxy ketones using an α-stannyl ester–stannous chloride system in a chelation-controlled manner

M. Yasuda, K. Okamoto, T. Sako and A. Baba, Chem. Commun., 2001, 157 DOI: 10.1039/B008493J

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