Issue 3, 2001
From the journal:

Chemical Communications

Fluorodesilylation of alkenyltrimethylsilanes: a new route to fluoroalkenes and difluoromethyl-substituted amides, alcohols or ethers

Benjamin Greedya  and  Veronique Gouverneur*a  

* Corresponding authors

a University of Oxford, The Dyson Perrins Laboratory, South Parks Road, Oxford, UK
E-mail: veronique.gouverneur@chem.ox.ac.uk
Fax: +44 1865 275 644
Tel: +44 1865 275 644

Abstract

A range of alkenyltrimethylsilanes are converted to alkenyl fluorides by reaction with one equivalent of Selectfluor™ (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)), or difluoromethyl-substituted alcohols, ethers or amides using an excess of Selectfluor™ in the presence of various nucleophiles.

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Article information

DOI
https://doi.org/10.1039/B009179K
Article type
Communication
Submitted
09 Nov 2000
Accepted
19 Dec 2000
First published
16 Jan 2001

Chem. Commun., 2001, 233-234

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Fluorodesilylation of alkenyltrimethylsilanes: a new route to fluoroalkenes and difluoromethyl-substituted amides, alcohols or ethers

B. Greedy and V. Gouverneur, Chem. Commun., 2001, 233 DOI: 10.1039/B009179K

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