Poly-carbon chemistry: reactions of the multi-sitecoordinated diyndiyl ligand in{Fe2(CO)6(μ-PPh2)}2(μ-η1,η2∶μ-η1,η2-CC–CC) with the nucleophilesP(OMe)3 and NHEt2

Paul J. Low; Arthur J. Carty; Konstantin A. Udachin; Gary D. Enright

doi:10.1039/B009797G

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Poly-carbon chemistry: reactions of the multi-site coordinated diyndiyl ligand in {Fe₂(CO)₆(μ-PPh₂)}₂(μ-η¹,η²∶μ-η¹,η²-CC–CC) with the nucleophiles P(OMe)₃ and NHEt₂Electronic supplementary information (ESI) available: reaction details and spectroscopic data. See http://www.rsc.org/suppdata/cc/b0/b009797g/

Paul J. Low,*^a Arthur J. Carty,*^a Konstantin A. Udachin^a and Gary D. Enright^a

Author affiliations

* Corresponding authors

^a Steacie Institute for Molecular Sciences, National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario, Canada

^b Department of Chemistry, University of Durham, South Road, Durham, UK
E-mail: p.j.low@durham.ac.uk

^c Ottawa-Carleton Research Institute, Department of Chemistry, University of Ottawa, 1125 Colonel By Drive, Ottawa, Ontario, Canada

Abstract

The diyndiyl complex {Fe₂(CO)₆(μ-PPh₂)}₂(μ-C [triple bond, length half m-dash] C–CC) reacts with P(OMe)₃ or NHEt₂ to give products derived from addition to C_α and facile P–C, N–C and/or C–C bond formation.

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Article information

DOI: https://doi.org/10.1039/B009797G
Article type: Communication
Submitted: 06 Dec 2000
Accepted: 22 Jan 2001
First published: 09 Feb 2001

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Chem. Commun., 2001, 411-412

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Poly-carbon chemistry: reactions of the multi-site coordinated diyndiyl ligand in {Fe₂(CO)₆(μ-PPh₂)}₂(μ-η¹,η²∶μ-η¹,η²-CC–CC) with the nucleophiles P(OMe)₃ and NHEt₂

P. J. Low, A. J. Carty, K. A. Udachin and G. D. Enright, Chem. Commun., 2001, 411 DOI: 10.1039/B009797G

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