Issue 7, 2001
From the journal:

Chemical Communications

Continuous platinum-catalyzed enantioselective hydrogenation in ‘supercritical’ solvents

Roland Wandeler,a   Niklaus Künzle,a   Michael S. Schneider,a   Tamas Mallata  and  Alfons Baiker*a  

* Corresponding authors

a Laboratory of Technical Chemistry, Swiss Federal Institute of Technology, ETH-Zentrum, Zürich, Switzerland.
E-mail: baiker@tech.chem.ethz.ch;
Fax: +41 1 6321163;
Tel: +41 1 6323153

Abstract

Hydrogenation of ethyl pyruvate in ‘supercritical’ ethane in a fixed bed reactor over cinchona-modified Pt/Al2O3 affords good ee at an exceptionally high rate, whereas in carbon dioxide the catalytic performance under similar conditions is inferior.

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Article information

DOI
https://doi.org/10.1039/B100511L
Article type
Communication
Submitted
15 Jan 2001
Accepted
06 Mar 2001
First published
21 Mar 2001

Chem. Commun., 2001, 673-674

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Continuous platinum-catalyzed enantioselective hydrogenation in ‘supercritical’ solvents

R. Wandeler, N. Künzle, M. S. Schneider, T. Mallat and A. Baiker, Chem. Commun., 2001, 673 DOI: 10.1039/B100511L

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