Acetonitrile oxide (2) is produced by the irradiation of the title azirine 1 in the presence of O2 in fluid solutions and in low-temperature matrices through the capture of the biradical 7 with O2, which is generated by the photochemical C–N bond cleavage of the azirine ring.
Photochemical generation of acetonitrile oxide via the C–N bond cleavage of 3-methyl-2-(4-nitrophenyl)-2H-azirine
H. Inui and S. Murata, Chem. Commun., 2001, 1036 DOI: 10.1039/B102384P
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
