Issue 13, 2001
From the journal:

Chemical Communications

Carbene transposition involving double dehydrogenation of an sp3 carbonElectronic supplementary information (ESI) available: synthetic and spectroscopic data. Crystallographic data and selected bond lengths and angle for B. See http://www.rsc.org/suppdata/cc/b1/b102422c/

Joseph N. Coalter III,a   John C. Huffmana  and  Kenneth G. Caulton*a  

* Corresponding authors

a Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, IN 47405-7102, USA.
E-mail: caulton@indiana.edu

Abstract

Two benzylic hydrogens of 2,6-Me2C6H3O− coordinated to RuCl(PCy3)2(CHPh)+ are transferred to the benzylidene ligand, liberating toluene to form a new carbene which is covalently linked to the aryloxide ligand.

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Article information

DOI
https://doi.org/10.1039/B102422C
Article type
Communication
Submitted
14 Mar 2001
Accepted
03 May 2001
First published
07 Jun 2001

Chem. Commun., 2001, 1158-1159

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Carbene transposition involving double dehydrogenation of an sp3 carbon

J. N. Coalter III, J. C. Huffman and K. G. Caulton, Chem. Commun., 2001, 1158 DOI: 10.1039/B102422C

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