Issue 16, 2001
From the journal:

Chemical Communications

Is MCM-41 really advantageous over amorphous silica? The case of grafted titanium epoxidation catalystsElectronic supplementary information (ESI) available: experimental details of preparation and characterisation of the catalysts, IR spectra and results of the cyclohexene epoxidation with TBHP. See http://www.rsc.org/suppdata/cc/b1/b103057b/

José M. Fraile,a   José I. García,a   José A. Mayoral,*a   Eugenio Vispe,a   D. R. Brownb  and  M. Naderib  

* Corresponding authors

a Departamento de Química Orgánica, Instituto de Ciencia de Materiales de Aragón, Facultad de Ciencias, Universidad de Zaragoza-C.S.I.C., Zaragoza, Spain.
E-mail: mayoral@posta.uniza.es

b Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield, UK

Abstract

MCM-41 can be used in the same way as amorphous silica for the preparation of supported titanium catalysts; MCM-41 does not show clear advantages over silica in epoxidation reactions with either TBHP or H2O2; only in one case is a positive effect observed and this involves the recycled catalyst with H2O2.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B103057B
Article type
Communication
Submitted
04 Apr 2001
Accepted
28 Jun 2001
First published
26 Jul 2001

Chem. Commun., 2001, 1510-1511

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Is MCM-41 really advantageous over amorphous silica? The case of grafted titanium epoxidation catalysts

J. M. Fraile, J. I. García, J. A. Mayoral, E. Vispe, D. R. Brown and M. Naderi, Chem. Commun., 2001, 1510 DOI: 10.1039/B103057B

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