Several cis-RuX2((R)-BINAP)(diimine) complexes have been prepared, and many of these exhibit an unusual temperature-dependent, accidental degeneracy of the 31P shifts in their solution NMR spectra.
A remarkable temperature-dependent, accidental degeneracy of 31P NMR chemical shifts in Ru(II) diphosphine/diimine complexes
P. W. Cyr, B. O. Patrick and B. R. James, Chem. Commun., 2001, 1570 DOI: 10.1039/B103473C
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