Cs1−xSn1−xBi9+xSe15 and Cs1.5−3xBi9.5+xSe15: members of the homologous superseries Am[M1+lSe2+l]2m[M1+2l+nSe3+3l+n] (A = alkali metal, M = Sn and Bi) allowing structural evolution in three different dimensions

Antje Mrotzek; Lykourgos Iordanidis; Mercouri G. Kanatzidis

doi:10.1039/B103870M

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Cs_1−xSn_1−xBi_9+xSe₁₅ and Cs_1.5−3xBi_9.5+xSe₁₅: members of the homologous superseries A_m[M_1+lSe_2+l] _2m[M_1+2l+nSe_3+3l
+n] (A = alkali metal, M = Sn and Bi) allowing structural evolution in three different dimensions

Antje Mrotzek,^a Lykourgos Iordanidis^a and Mercouri G. Kanatzidis*^a

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* Corresponding authors

^a Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, MI, USA.
E-mail: kanatzid@cem.msu.edu

Abstract

Cs_1−xSn_1−xBi_9+xSe₁₅ and Cs_1.5−3xBi_9.5+xSe₁₅ crystallize in a new structure type which does not belong to but is closely related to the members of the homologous series A_m[M₆- Se₈]_m[M_5+nSe_9+
n]; the new phases reveal a third dimension of structural evolution for this series according to the formula A_m[M_1+lSe_2+l] _2m[M_{1+2l +
n}Se_3+3l+n].

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Supplementary files

Crystal structure data TXT (46K)

Article information

DOI: https://doi.org/10.1039/B103870M
Article type: Communication
Submitted: 21 Mar 2001
Accepted: 13 Jun 2001
First published: 16 Aug 2001

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Chem. Commun., 2001, 1648-1649

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Cs_1−xSn_1−xBi_9+xSe₁₅ and Cs_1.5−3xBi_9.5+xSe₁₅: members of the homologous superseries A_m[M_1+lSe_2+l] _2m[M_1+2l+nSe_3+3l
+n] (A = alkali metal, M = Sn and Bi) allowing structural evolution in three different dimensions

A. Mrotzek, L. Iordanidis and M. G. Kanatzidis, Chem. Commun., 2001, 1648 DOI: 10.1039/B103870M

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