Issue 18, 2001
From the journal:

Chemical Communications

Novel silver(i)–organic coordination polymers: conversion of extended structures in the solid state as driven by argentophilic interactions

Long Pan,a   E. Brice Woodlock,a   Xiaotai Wang,*a   Kin-Chung Lamb  and  Arnold L. Rheingoldb  

* Corresponding authors

a Department of Chemistry, Campus Box 194, University of Colorado at Denver, P.O. Box 173364, Denver, Colorado, USA.
E-mail: xwang@carbon.cudenver.edu

b Department of Chemistry and Biochemistry, University of Delaware, Newark, USA

Abstract

Structurally distinct coordination polymers [Ag(bpp)]ClO41 and [Ag(bpp)]PF62 [bpp = 1,3-bis(4-pyridyl)propane] have been assembled; the conversion of 1 into 2 on treatment with NaPF6 is driven by argentophilic interactions and is the first such transformation reported for silver(I)–organic coordination polymers.

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Article information

DOI
https://doi.org/10.1039/B104074J
Article type
Communication
Submitted
27 Apr 2001
Accepted
13 Jul 2001
First published
23 Aug 2001

Chem. Commun., 2001, 1762-1763

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Novel silver(I)–organic coordination polymers: conversion of extended structures in the solid state as driven by argentophilic interactions

L. Pan, E. B. Woodlock, X. Wang, K. Lam and A. L. Rheingold, Chem. Commun., 2001, 1762 DOI: 10.1039/B104074J

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