Issue 18, 2001

Addition of diprotic nucleophiles to a C60–tetrazine monoadduct: structural reassignment and correction of a novel rearrangementElectronic supplementary information (ESI) available: select spectroscopic data for (±)-2, 3 and (±)-4. See http://www.rsc.org/suppdata/cc/b1/b104151g/

Abstract

C60–tetrazine Diels–Alder adducts bearing electron deficient dihydropyridazine groups undergo chemoselective amination and hydration reactions upon addition of primary aliphatic amines and water, respectively, to form new adducts with 4,5-dihydropyrazole groups nested atop the [60]fullerene skeleton.

Supplementary files

Article information

Article type
Communication
Submitted
09 May 2001
Accepted
18 Jul 2001
First published
29 Aug 2001

Chem. Commun., 2001, 1758-1759

Addition of diprotic nucleophiles to a C60–tetrazine monoadduct: structural reassignment and correction of a novel rearrangement

G. P. Miller, M. C. Tetreau, M. M. Olmstead, P. A. Lord and A. L. Balch, Chem. Commun., 2001, 1758 DOI: 10.1039/B104151G

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