Crystal structure of the two-dimensional framework [Mn(salen)]4n[Re6Te8(CN)6 ]n [salen = N,N′-ethylenebis(salicylideneaminato)]
Abstract
The first complex-bridged cyano–rhenium cluster framework material [Mn(salen)]4n[Re6Te8(CN)6 ]n, with a two-dimensional layered structure is prepared by the reaction of a methanol solution of [Mn(salen)]ClO4 with an aqueous solution of Na4[Re6Te8(CN)6].