Issue 18, 2001
From the journal:

Chemical Communications

Enantioselective deprotonation reactions using polymer-supported chiral magnesium amide basesElectronic supplementary information (ESI) available: representative experimental procedure. See http://www.rsc.org/suppdata/cc/b1/b104417f/

Kenneth W. Henderson,*a   William J. Kerr*a  and  Jennifer H. Moira  

* Corresponding authors

a Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Scotland, Glasgow, UK
E-mail: w.kerr@strath.ac.uk

Abstract

Novel and readily accessible polymer-supported chiral magnesium amide reagents have been prepared and shown to be effective in the asymmetric deprotonation of a series of prochiral cyclohexanones, affording good to excellent levels of both conversion and enantiomeric ratio (up to 93∶7); the Merrifield-based chiral amine species has been shown to be readily recyclable.

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Article information

DOI
https://doi.org/10.1039/B104417F
Article type
Communication
Submitted
18 May 2001
Accepted
25 Jul 2001
First published
28 Aug 2001

Chem. Commun., 2001, 1722-1723

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Enantioselective deprotonation reactions using polymer-supported chiral magnesium amide bases

K. W. Henderson, W. J. Kerr and J. H. Moir, Chem. Commun., 2001, 1722 DOI: 10.1039/B104417F

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