Issue 17, 2001
From the journal:

Chemical Communications

NMR evidence of pentaoxo organosilicon complexes in dilute neutral aqueous silicate solutions

Stephen D. Kinrade,*a   Andrew S. Schach,a   Robin J. Hamiltona  and  Christopher T. G. Knightb  

* Corresponding authors

a Department of Chemistry, Lakehead University, Thunder Bay, ON P7B5E1, Canada.
E-mail: Stephen.Kinrade@lakeheadu.ca

b School of Chemical Sciences, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA

Abstract

Silicon-29 NMR spectra of a neutral, dilute aqueous silicic acid solution, with a pH and Si concentration typical of soil solutions, reveal that a significant fraction of the silicon is incorporated in two five-coordinated organosilicon complexes when sodium gluconate is present.

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Article information

DOI
https://doi.org/10.1039/B104713M
Article type
Communication
Submitted
30 May 2001
Accepted
02 Jul 2001
First published
03 Aug 2001

Chem. Commun., 2001, 1564-1565

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NMR evidence of pentaoxo organosilicon complexes in dilute neutral aqueous silicate solutions

S. D. Kinrade, A. S. Schach, R. J. Hamilton and C. T. G. Knight, Chem. Commun., 2001, 1564 DOI: 10.1039/B104713M

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