Issue 19, 2001
From the journal:

Chemical Communications

Dioxygen activation by a neutral β-diketiminato copper(i) ethylene complexElectronic supplementary information (ESI) available: synthesis of Tl[Me2NN] and 1–3 with relevant analytical and spectroscopic details. See http://www.rsc.org/suppdata/cc/b1/b105244f/

Xuliang Daia  and  Timothy H. Warren*a  

* Corresponding authors

a Georgetown University, Department of Chemistry, Box 571227, Washington, D.C., USA.
E-mail: thw@georgetown.edu

Abstract

The synthesis and structure of two thermally stable neutral β-diketiminato copper(I) olefin complexes are presented along with the structure of a Cu(II)2(μ-OH)2 dimer that results from the reaction of the Cu(I) ethylene complex with O2via the proposed intermediacy of a Cu(III)2(μ-O)2 species.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B105244F
Article type
Communication
Submitted
14 Jun 2001
Accepted
15 Aug 2001
First published
18 Sep 2001

Chem. Commun., 2001, 1998-1999

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Dioxygen activation by a neutral β-diketiminato copper(I) ethylene complex

X. Dai and T. H. Warren, Chem. Commun., 2001, 1998 DOI: 10.1039/B105244F

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