Issue 21, 2001
From the journal:

Chemical Communications

Highly effective epoxidation of alkenes with Ti-containing soluble polymers

G. Blanco-Brieva,a   J. M. Campos-Martín,a   M. P. de Frutosb  and  J. L. G. Fierro*a  

* Corresponding authors

a Instituto de Catálisis y Petroleoquímica, CSIC, Campus Cantoblanco, Madrid, Spain.
E-mail: jlgfierro@icp.csic.es;
Fax: +34 915854760

b Centro de Investigación y Desarrollo, Repsol-YPF, Embajadores 183, Madrid, Spain

Abstract

Ti-containing polysiloxane epoxidation catalysts have been prepared by controlled hydrolysis of titanium- and alkylsilane precursors. These polysiloxanes exhibit very high yields to epoxides in the epoxidation reaction of primary alkenes with organic hydroperoxides.

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Article information

DOI
https://doi.org/10.1039/B105362K
Article type
Communication
Submitted
19 Jun 2001
Accepted
13 Sep 2001
First published
15 Oct 2001

Chem. Commun., 2001, 2228-2229

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Highly effective epoxidation of alkenes with Ti-containing soluble polymers

G. Blanco-Brieva, J. M. Campos-Martín, M. P. de Frutos and J. L. G. Fierro, Chem. Commun., 2001, 2228 DOI: 10.1039/B105362K

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