Issue 22, 2001
From the journal:

Chemical Communications

Stereospecific oxidation by Compound I of Cytochrome P450 does not proceed in a concerted synchronous manner

Sam P. de Visser,a   François Ogliaroa  and  Sason Shaik*a  

* Corresponding authors

a Department of Organic Chemistry and the, Lise Meitner-Minerva Center for Computational Quantum Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel.
E-mail: sason@yfaat.ch.huji.ac.il;
Fax: +972-2-6584680;
Tel: +972-2-6585909

Abstract

Calculations show that the transition structure for the synchronous oxygen transfer by Compound I is a second order saddle point. The process is unlikely.

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Article information

DOI
https://doi.org/10.1039/B105571M
Article type
Communication
Submitted
26 Jun 2001
Accepted
01 Oct 2001
First published
26 Oct 2001

Chem. Commun., 2001, 2322-2323

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Stereospecific oxidation by Compound I of Cytochrome P450 does not proceed in a concerted synchronous manner

S. P. de Visser, F. Ogliaro and S. Shaik, Chem. Commun., 2001, 2322 DOI: 10.1039/B105571M

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