Issue 22, 2001
From the journal:

Chemical Communications

Conjugate addition of arylsilanes to unsaturated carbonyl compounds catalyzed by rhodium in air and water

Tai-Sheng Huanga  and  Chao-Jun Li*a  

* Corresponding authors

a Department of Chemistry, Tulane University, New Orleans, Louisiana, 70118.
E-mail: cjli@tulane.edu

Abstract

ArSiCl3 and Ar2SiCl2, believed to be unstable in aqueous media, reacted efficiently with α,β-unsaturated ketones and esters in air and water (in the presence of sodium fluoride and a rhodium catalyst), giving good to excellent yields of the desired conjugate addition products.

Graphical abstract: Conjugate addition of arylsilanes to unsaturated carbonyl compounds catalyzed by rhodium in air and water

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Article information

DOI
https://doi.org/10.1039/B106768K
Article type
Communication
Submitted
10 Jul 2001
Accepted
19 Sep 2001
First published
22 Oct 2001

Chem. Commun., 2001, 2348-2349

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Conjugate addition of arylsilanes to unsaturated carbonyl compounds catalyzed by rhodium in air and water

T. Huang and C. Li, Chem. Commun., 2001, 2348 DOI: 10.1039/B106768K

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