Issue 22, 2001
From the journal:

Chemical Communications

Chelating alkoxy-N-heterocyclic carbene complexes of silver and copperElectronic supplementary information (ESI) available: spectroscopic data for 1–3, cyclic voltammetry. See http://www.rsc.org/suppdata/cc/b1/b107855k/

Polly L. Arnold,*a   Andrew C. Scarisbrick,a   Alexander J. Blakea  and  Claire Wilsona  

* Corresponding authors

a School of Chemistry, The University of Nottingham, University Park, Nottingham, UK
E-mail: Polly.Arnold@nott.ac.uk

Abstract

Incorporation of an alkoxide functional group into an N-heterocyclic carbene (NHC) ligand allows the synthesis of the first anionic NHC chelating ligands, which react to give the first neutral, molecular silver(I) alkoxide carbene complex, and a copper(I) derivative containing the first non-macrocyclic, square planar Cu(I) centres.

Graphical abstract: Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper

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Article information

DOI
https://doi.org/10.1039/B107855K
Article type
Communication
Submitted
31 Aug 2001
Accepted
27 Sep 2001
First published
22 Oct 2001

Chem. Commun., 2001, 2340-2341

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Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper

P. L. Arnold, A. C. Scarisbrick, A. J. Blake and C. Wilson, Chem. Commun., 2001, 2340 DOI: 10.1039/B107855K

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