Issue 24, 2001
From the journal:

Chemical Communications

Formation of different framework structured dimeric dianions formed from the reduction of 2,4,6-tricyano-1,3,5-triazine and 1,3,5-tricyanobenzene†

Rico E. Del Sesto,a   Atta M. Arifa  and  Joel S. Miller*a  

* Corresponding authors

a Department of Chemistry, University of Utah, 315 S. 1400 E. RM 2124, Salt Lake City, Utah, 84112-0850, USA
E-mail: jsmiller@chemistry.utah.edu

Abstract

Reduction of 2,4,6-tricyano-1,3,5-triazine (1) and 1,3,5-tricyanobenzene (2) leads to dianionic dimers with long, ∼1.57 Å, central C–C bonds. In contrast to 1, which dimerizes at the nitrile substituted carbon, 2 has a different motif as it dimerizes at the hydrogen substituted carbon.

Graphical abstract: Formation of different framework structured dimeric dianions formed from the reduction of 2,4,6-tricyano-1,3,5-triazine and 1,3,5-tricyanobenzene

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Article information

DOI
https://doi.org/10.1039/B108297N
Article type
Communication
Submitted
11 Sep 2001
Accepted
15 Oct 2001
First published
28 Nov 2001

Chem. Commun., 2001, 2730-2731

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Formation of different framework structured dimeric dianions formed from the reduction of 2,4,6-tricyano-1,3,5-triazine and 1,3,5-tricyanobenzene

R. E. Del Sesto, A. M. Arif and J. S. Miller, Chem. Commun., 2001, 2730 DOI: 10.1039/B108297N

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