Issue 17, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

An unprecedented six-fold anion-type chiral diamondoid-like eight-coordinate Cd(II) coordination polymer with a second-order nonlinear optical effect

Zhen-Feng Chen,a   Ren-Gen Xiong,*a   Brendan F. Abrahams,*b   Xiao-Zeng You*a  and  Chi-Ming Chec  

* Corresponding authors

a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, PR China

b School of Chemistry, University of Melbourne, Parkville, Victoria, Australia

c Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong

Abstract

The reaction of Cd(OH)2 with 3,3′-azodibenzoic acid affords an unprecedented anionic chiral diamondoid network, bis(3,3′-azodibenzoate)cadmium·(H2NMe2)·(NH4) which contains eight-coordinate cadmium and displays strong SHG response and enantioselectivity for organic amines.

Graphical abstract: An unprecedented six-fold anion-type chiral diamondoid-like eight-coordinate Cd(II) coordination polymer with a second-order nonlinear optical effect

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Article information

DOI
https://doi.org/10.1039/B105130J
Article type
Communication
Submitted
12 Jun 2001
Accepted
19 Jul 2001
First published
06 Aug 2001

J. Chem. Soc., Dalton Trans., 2001, 2453-2455

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An unprecedented six-fold anion-type chiral diamondoid-like eight-coordinate Cd(II) coordination polymer with a second-order nonlinear optical effect

Z. Chen, R. Xiong, B. F. Abrahams, X. You and C. Che, J. Chem. Soc., Dalton Trans., 2001, 2453 DOI: 10.1039/B105130J

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