Synthesis and properties of novel donor-type metal–dithiolene complexes based on 5,6-dihydro-1,4-dioxine-2,3-dithiol (edo) ligand

Eiji Watanabe; Masahiro Fujiwara; Jun-Ichi Yamaura; Reizo Kato

doi:10.1039/B102000P

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Eiji Watanabe,^a Masahiro Fujiwara,^a Jun-Ichi Yamaura^a and Reizo Kato*^b

Author affiliations

* Corresponding authors

^a The Institute for Solid State Physics, The University of Tokyo, Kashiwa-shi, Chiba, Japan

^b RIKEN (The Institute of Physical and Chemical Research), Hirosawa, Saitama, Japan
E-mail: reizo@postman.riken.go.jp

Abstract

A novel donor-type metal–dithiolene complex, Ni(edo)₂ [edo = 5,6-dihydro-1,4-dioxine-2,3-dithiolate], and its mixed-ligand derivatives were synthesized and characterized. Their improved solubility and donor abilities have been confirmed. They provide various types of radical cation salts which exhibit novel donor arrangements.

This article is part of the themed collection: Metal-organic conductors (enriched issue)

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Article information

DOI: https://doi.org/10.1039/B102000P
Article type: Paper
Submitted: 06 Mar 2001
Accepted: 02 May 2001
First published: 08 Jun 2001

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J. Mater. Chem., 2001,11, 2131-2141

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