Issue 7, 2002
From the journal:

Chemical Communications

A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions. Polar and enthalpic effects

Francesco Minisci,*a   Carlo Punta,a   Francesco Recupero,a   Francesca Fontanaa  and  Gian Franco Pedullia  

* Corresponding authors

a Dipartimento di Chimica del Politecnico, via Mancinelli 7, I-20131, Milano MI, Italy
E-mail: francesco.minisci@polimi.it

b Università di Bergamo, Dipartimento di Ingegneria, viale Marconi 5, I-24044, Dalmine BG, Italy

c Università di Bologna, Dipartimento di Chimica Organica ‘A.Mangini’, via S.Donato 15, I-40127, Bologna BO, Italy

Abstract

A new selective synthesis of aromatic aldehydes is described, based on catalytic oxidation of benzyl alcohols with molecular oxygen at rt and atmospheric pressure.

Graphical abstract: A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions. Polar and enthalpic effects

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Article information

DOI
https://doi.org/10.1039/B110451A
Article type
Communication
Submitted
14 Nov 2001
Accepted
06 Feb 2002
First published
04 Mar 2002

Chem. Commun., 2002, 688-689

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A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions. Polar and enthalpic effects

F. Minisci, C. Punta, F. Recupero, F. Fontana and G. F. Pedulli, Chem. Commun., 2002, 688 DOI: 10.1039/B110451A

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