Issue 4, 2002
From the journal:

Chemical Communications

Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex

Jonghyuk Lee,a   Brendan Twamleyb  and  George B. Richter-Addo*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, Oklahoma, USA
E-mail: grichteraddo@ou.edu

b X-ray Structural Laboratory, University Research Office, 109 Morrill Hall, University of Idaho, Moscow, Idaho, USA

Abstract

The metalloporphyrin nitrone complexes [M(oep)(CO)(DMPO)] (M = Ru, Os; oep = octaethylporphyrinato dianion; DMPO = 5,5-dimethyl-1-pyrroline N-oxide) have been prepared: the crystal structure of the Ru complex reveals a sole η1-O binding mode of the nitrone ligand to the metal center.

Graphical abstract: Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex

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Article information

DOI
https://doi.org/10.1039/B111057H
Article type
Communication
Submitted
05 Dec 2001
Accepted
14 Jan 2002
First published
31 Jan 2002

Chem. Commun., 2002, 380-381

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Nitrones are suitable ligands for heme models: X-ray crystal structure of the first metalloporphyrin nitrone complex

J. Lee, B. Twamley and G. B. Richter-Addo, Chem. Commun., 2002, 380 DOI: 10.1039/B111057H

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