Issue 6, 2002
From the journal:

Chemical Communications

1∶1 Complexes of 5-(4-[N-tert-butyl-N-aminoxyl]phenyl)pyrimidine with manganese(ii) and copper(ii) hexafluoroacetonylacetonate†

Lora M. Field,a   Paul M. Lahti*a  and  Fernando Palaciob  

* Corresponding authors

a Department of Chemistry, University of Massachusetts, Amherst, USA
E-mail: lahti@chem.umass.edu

b Instituto de Ciencia de Materiales de Aragón, CSIC – Universidad de Zaragoza, Zaragoza, Spain
E-mail: palacio@posta.unizar.es

Abstract

Mn(hfac)2 and Cu(hfac)2 form 1∶1 complexes with 5-(4-[N-tert-butyl-N-aminoxyl]phenyl)pyrimidine that exhibit strong metal–nitroxide exchange; spin polarization models do not explain the antiferromagnetic exchange behavior between spin sites in these complexes.

Graphical abstract: 1∶1 Complexes of 5-(4-[N-tert-butyl-N-aminoxyl]phenyl)pyrimidine with manganese(ii) and copper(ii) hexafluoroacetonylacetonate

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Article information

DOI
https://doi.org/10.1039/B111295N
Article type
Communication
Submitted
07 Dec 2001
Accepted
24 Jan 2002
First published
25 Feb 2002

Chem. Commun., 2002, 636-637

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1∶1 Complexes of 5-(4-[N-tert-butyl-N-aminoxyl]phenyl)pyrimidine with manganese(II) and copper(II) hexafluoroacetonylacetonate

L. M. Field, P. M. Lahti and F. Palacio, Chem. Commun., 2002, 636 DOI: 10.1039/B111295N

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