Issue 6, 2002
From the journal:

Chemical Communications

A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide π-donor ancillary ligand†‡

Winfried P. Kretschmer,*a   Chris Dijkhuis,a   Auke Meetsma,a   Bart Hessena  and  Jan H. Teubena  

* Corresponding authors

a Dutch Polymer Institute/Centre for Catalytic Olefin Polymerisation, Stratingh Institute of Chemistry and Chemical Engineering, University of Groningen, Nijenborgh 4, AG Groningen, The Netherlands
E-mail: kretschmer@chem.rug.nl

Abstract

The titanium complex Cp[1,3-(2′,6′-Me2C6H3)2(CH2N)2C[double bond, length as m-dash]N]Ti(CH2Ph)2, with a monoanionic η1-iminoimidazolidide ancillary ligand, is shown to be a highly efficient catalyst for olefin polymerisation when activated with the Lewis acid B(C6F5)3.

Graphical abstract: A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide π-donor ancillary ligand

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Article information

DOI
https://doi.org/10.1039/B111343G
Article type
Communication
Submitted
12 Dec 2001
First published
25 Feb 2002

Chem. Commun., 2002, 608-609

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A highly efficient titanium-based olefin polymerisation catalyst with a monoanionic iminoimidazolidide π-donor ancillary ligand

W. P. Kretschmer, C. Dijkhuis, A. Meetsma, B. Hessen and J. H. Teuben, Chem. Commun., 2002, 608 DOI: 10.1039/B111343G

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