Issue 6, 2002
From the journal:

Chemical Communications

Remarkable co-catalysis by copper(i) oxide in the palladium catalyzed cross-coupling of arylboronic acids with ethyl bromoacetate†

Xing-xin Liua  and  Min-zhi Deng*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academic Sinica, 354 Fenglin Lu, Shanghai 200032, P.R. China
E-mail: dengmz@pub.sioc.ac.cn
Fax: 86-21-64166128
Tel: 86-21-64163300-3425

Abstract

Copper(I) oxide can effectively co-catalyze the Suzuki type cross-coupling reactions of arylboronic acids with ethyl bromoacetate. As an alternative protocol for introducing the methylenecarboxy group into functionalized molecules, this reaction occurs in the absence of highly toxic thallium compounds or special ligands and should be convenient and practical.

Graphical abstract: Remarkable co-catalysis by copper(i) oxide in the palladium catalyzed cross-coupling of arylboronic acids with ethyl bromoacetate

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Article information

DOI
https://doi.org/10.1039/B111355K
Article type
Communication
Submitted
14 Dec 2001
Accepted
07 Feb 2002
First published
22 Feb 2002

Chem. Commun., 2002, 622-623

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Remarkable co-catalysis by copper(I) oxide in the palladium catalyzed cross-coupling of arylboronic acids with ethyl bromoacetate

X. Liu and M. Deng, Chem. Commun., 2002, 622 DOI: 10.1039/B111355K

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