From a consideration of the interactions between non-covalent bonds, it is concluded that positively cooperative binding will occur with a benefit in enthalpy and a cost in entropy, and that negatively cooperative binding will occur with a cost in enthalpy and a benefit in entropy;
D. H. Williams, C. T. Calderone, D. P. O’Brien and R. Zerella, Chem. Commun., 2002, 1266 DOI: 10.1039/B201428A
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