Microwave-assisted simple ion-exchange of ZSM-5-type zeolites with copper ions and their specific adsorption properties for N2 molecules at room temperature

Abstract

Copper ion-exchanged ZSM-5 samples, prepared using an easy method that takes advantage of microwaves, exhibit a quite peculiar adsorption feature for dinitrogen molecules, in that a large volume of chemisorbed N₂ was detected, even at room temperature, and the specificity of the adsorption properties was clarified by comparing with the properties of samples prepared by an ordinary ion-exchange method.