Issue 16, 2002
From the journal:

Chemical Communications

Triphenylmethyldifluoramine: a stable reagent for the synthesis of gem-bis(difluoramines)†

G. K. Surya Prakash,*a   Markus Etzkorn,a   George A. Olah,*a   Karl O. Christe,ab   Stefan Schneidera  and  Ashwani Vijb  

* Corresponding authors

a Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA, USA
E-mail: gprakash@usc.edu
Fax: +1 213 740 6270
Tel: +1 213 740 5984

b Air Force Research Laboratory, Edwards Air Force Base, CA, USA

Abstract

The conversion of ketones into geminal bis(difluoramines) can be achieved under mild two-phase reaction conditions by employing triphenylmethyldifluoramine as an in situ source of difluoramine.

Graphical abstract: Triphenylmethyldifluoramine: a stable reagent for the synthesis of gem-bis(difluoramines)

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Article information

DOI
https://doi.org/10.1039/B203811K
Article type
Communication
Submitted
16 Apr 2002
Accepted
13 Jun 2002
First published
10 Jul 2002

Chem. Commun., 2002, 1712-1713

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Triphenylmethyldifluoramine: a stable reagent for the synthesis of gem-bis(difluoramines)

G. K. S. Prakash, M. Etzkorn, G. A. Olah, K. O. Christe, S. Schneider and A. Vij, Chem. Commun., 2002, 1712 DOI: 10.1039/B203811K

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