Unusual properties of the first copper complex containing a π(η2)-coordinated phosphorus–carbon double bond moiety

Dietrich Gudat; Martin Nieger; Katja Schmitz; Laslo Szarvas

doi:10.1039/B204144H

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Unusual properties of the first copper complex containing a π(η²)-coordinated phosphorus–carbon double bond moiety†

Dietrich Gudat,*^a Martin Nieger,^a Katja Schmitz^a and Laslo Szarvas^a

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* Corresponding authors

^a Universität Bonn, Institut für Anorganische Chemie, Gerhard-Domagk-Str. 1, Bonn, Germany
E-mail: dgudat@uni-bonn.de
Fax: ++49 228 73 5327

Abstract

The first stable phosphaarene π-complex of copper displays unusual ³¹P NMR data that suggest a novel interpretation of ³¹P coordination shifts in π-complexes of phosphorus containing multiple bonds.

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Article information

DOI: https://doi.org/10.1039/B204144H
Article type: Communication
Submitted: 01 May 2002
Accepted: 03 Jul 2002
First published: 19 Jul 2002

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Chem. Commun., 2002, 1820-1821

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Unusual properties of the first copper complex containing a π(η²)-coordinated phosphorus–carbon double bond moiety

D. Gudat, M. Nieger, K. Schmitz and L. Szarvas, Chem. Commun., 2002, 1820 DOI: 10.1039/B204144H

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