Issue 17, 2002
From the journal:

Chemical Communications

A π-stacked 1,2,3-dithiazolyl radical. Preparation and solid state characterization of (Cl2C3NS)(ClC2NS2)

Leanne Beer,a   A. Wallace Cordes,b   Robert C. Haddon,c   Mikhail E. Itkis,c   Richard T. Oakley,*a   Robert W. Reeda  and  Craig M. Robertsona  

* Corresponding authors

a Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada
E-mail: oakley@sciborg.uwaterloo.ca

b Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, Arkansas 72701, USA

c Departments of Chemistry and Environmental Engineering, University of California, Riverside, California 92521, USA

Abstract

Crystals of (Cl2C3NS)(ClC2NS2), an isothiazolyl-substituted 1,2,3-dithiazolyl radical, consist of evenly spaced, slipped π-stacks; magnetic and conductivity measurements indicate the material is a Mott insulator with σRT = 2 × 10−7 S cm−1.

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Article information

DOI
https://doi.org/10.1039/B204855H
Article type
Communication
Submitted
21 May 2002
Accepted
08 Jul 2002
First published
25 Jul 2002

Chem. Commun., 2002, 1872-1873

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A π-stacked 1,2,3-dithiazolyl radical. Preparation and solid state characterization of (Cl2C3NS)(ClC2NS2)

L. Beer, A. Wallace Cordes, R. C. Haddon, M. E. Itkis, R. T. Oakley, R. W. Reed and C. M. Robertson, Chem. Commun., 2002, 1872 DOI: 10.1039/B204855H

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