Issue 16, 2002
From the journal:

Chemical Communications

DNA oxidation by peroxo-chromium(v) species: oxidation of guanosine to guanidinohydantoin

Lamis Joudah,a   Shadi Moghaddasa  and  Rathindra N. Bose*a  

* Corresponding authors

a Department of Chemistry, Kent State University, Kent, OH, USA
E-mail: rbose@kent.edu
Fax: Fax: 1 330 672 3816
Tel: 1 330 672 0700

Abstract

Reactions of peroxo-chromium(V) complexes with DNA afforded mainly guanine oxidation yielding, a four-electron oxidation product, guanidinohydantoin, and exhibited extensive base labile strand scission.

Graphical abstract: DNA oxidation by peroxo-chromium(v) species: oxidation of guanosine to guanidinohydantoin

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Article information

DOI
https://doi.org/10.1039/B205407H
Article type
Communication
Submitted
05 Jun 2002
Accepted
24 Jun 2002
First published
11 Jul 2002

Chem. Commun., 2002, 1742-1743

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DNA oxidation by peroxo-chromium(V) species: oxidation of guanosine to guanidinohydantoin

L. Joudah, S. Moghaddas and R. N. Bose, Chem. Commun., 2002, 1742 DOI: 10.1039/B205407H

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