Issue 18, 2002
From the journal:

Chemical Communications

1-D polymer containing the [Ru–N–Ru] μ-nitrido moiety: crystal structure and magnetic properties of {[Cu(en)2]3[Ru2N(CN)10]·ClO4}n (en = 1,2-diaminoethane)†

Xian-Ru Sun,ac   Jiang-Lin Liang,a   Chi-Ming Che,*a   Nianyong Zhu,a   X. X. Zhangb  and  Song Gaoc  

* Corresponding authors

a Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong SAR, P. R. China
E-mail: cmche@hku.hk
Fax: +852 2857-1586

b Department of Physics, Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong SAR, P. R. China

c State Key Laboratory of Rare Earth Materials Chemistry and Application & PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing, P. R. China

Abstract

A novel (μ-nitrido–diruthenium)-bridged 1-D coordination polymer was formed from reaction of K5[Ru2N(CN)10] with [Cu(en)2](ClO4)2; a similar reaction with [Cu(pn)2][(ClO4)2] (pn = 1,3-diaminopropane) gave {[Cu(pn)2]5[Ru2N(CN)10]2} as a discrete molecular compound; variable temperature susceptibility measurements show that there is a weak ferromagnetic interaction between the Cu(II) ions in 1-D polymer.

Graphical abstract: 1-D polymer containing the [Ru–N–Ru] μ-nitrido moiety: crystal structure and magnetic properties of {[Cu(en)2]3[Ru2N(CN)10]·ClO4}n (en = 1,2-diaminoethane)

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B205534C
Article type
Communication
Submitted
07 Jun 2002
Accepted
07 Aug 2002
First published
19 Aug 2002

Chem. Commun., 2002, 2090-2091

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1-D polymer containing the [Ru–N–Ru] μ-nitrido moiety: crystal structure and magnetic properties of {[Cu(en)2]3[Ru2N(CN)10]·ClO4}n (en = 1,2-diaminoethane)

X. Sun, J. Liang, C. Che, N. Zhu, X. X. Zhang and S. Gao, Chem. Commun., 2002, 2090 DOI: 10.1039/B205534C

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