Issue 21, 2002
From the journal:

Chemical Communications

Terminal ruthenium carbido complexes as σ-donor ligands†

Andrew Hejl,a   Tina M. Trnka,a   Michael W. Daya  and  Robert H. Grubbs*a  

* Corresponding authors

a Arnold and Mabel Beckman Laboratory of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
E-mail: rhg@its.caltech.edu

Abstract

The terminal carbido ligand of (PCy3)2(Cl)2RuC coordinates to other metal centers in a σ-donor fashion, as in (PCy3)2(Cl)2Ru[triple bond, length as m-dash]C–Pd(Cl)2(SMe2) and (PCy3)2(Cl)2Ru[triple bond, length as m-dash]C–Mo(CO)5.

Graphical abstract: Terminal ruthenium carbido complexes as σ-donor ligands

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Article information

DOI
https://doi.org/10.1039/B207903H
Article type
Communication
Submitted
13 Aug 2002
Accepted
06 Sep 2002
First published
30 Sep 2002

Chem. Commun., 2002, 2524-2525

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Terminal ruthenium carbido complexes as σ-donor ligands

A. Hejl, T. M. Trnka, M. W. Day and R. H. Grubbs, Chem. Commun., 2002, 2524 DOI: 10.1039/B207903H

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