Issue 1, 2003
From the journal:

Chemical Communications

A novel layered oxysulfide intergrowth compound Sr4Mn2Cu5O4S5 containing a fragment of the α-Cu2S antifluorite structure

Nicolas Barriera  and  Simon J. Clarke*a  

* Corresponding authors

a Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
E-mail: simon.clarke@chem.ox.ac.uk
Fax: 44 1865 272690
Tel: 44 1865 272600

Abstract

Sr4Mn2Cu5O4S5 contains manganese oxide sheets separated by unusual antifluorite-type Cu3S3 layers in which copper(I) ions are distributed over three- and four-coordinate sites in a similar fashion to in α-Cu2−xS and suggestive of high two-dimensional copper ion mobility.

Graphical abstract: A novel layered oxysulfide intergrowth compound Sr4Mn2Cu5O4S5 containing a fragment of the α-Cu2S antifluorite structure

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Article information

DOI
https://doi.org/10.1039/B209747H
Article type
Communication
Submitted
07 Oct 2002
Accepted
11 Nov 2002
First published
02 Dec 2002

Chem. Commun., 2003, 164-165

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A novel layered oxysulfide intergrowth compound Sr4Mn2Cu5O4S5 containing a fragment of the α-Cu2S antifluorite structure

N. Barrier and S. J. Clarke, Chem. Commun., 2003, 164 DOI: 10.1039/B209747H

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