Issue 2, 2003

Photochemical and thermal ligand exchange in a ruthenium(ii) complex based on a scorpionate terpyridineligand

Abstract

A ruthenium(II) complex containing a 1,10-phenanthroline unit and a terpyridine fragment covalently linked to a benzonitrile group has been synthesised; coordination and decoordination of the benzonitrile group can be induced thermally and photochemically respectively, in an acetone–water mixture.

Graphical abstract: Photochemical and thermal ligand exchange in a ruthenium(ii) complex based on a scorpionate terpyridine ligand

Supplementary files

Article information

Article type
Communication
Submitted
28 Oct 2002
Accepted
27 Nov 2002
First published
16 Dec 2002

Chem. Commun., 2003, 188-189

Photochemical and thermal ligand exchange in a ruthenium(II) complex based on a scorpionate terpyridine ligand

E. R. Schofield, J. Collin, N. Gruber and J. Sauvage, Chem. Commun., 2003, 188 DOI: 10.1039/B210607H

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