Issue 8, 2003
From the journal:

Chemical Communications

A novel type of phosphide: synthesis and X-ray crystal structure analysis of (tBu3Si)3P4Li3

Hans-Wolfram Lerner,*a   Matthias Wagnera  and  Michael Bolteb  

* Corresponding authors

a Institut für Anorganische Chemie, Johann Wolfgang Goethe-Universität Frankfurt am Main, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

b Institut für Organische Chemie, Johann Wolfgang Goethe-Universität Frankfurt am Main, Marie-Curie-Straße 11, 60439 Frankfurt am Main, Germany

Abstract

The tetraphosphides (tBu3Si)3P4M3 (M = Li, Na) and (tBu2PhSi)3P4Na3 have been synthesized in high yield from the reaction of 3 equivalents of the silanides tBu3SiM (M = Li, Na) and tBu2PhSiNa with P4 in benzene. (tBu3Si)3P4M3 (M = Li, Na) are transformed into the unsaturated triphosphides (tBu3Si)2P3M (M = Li, Na) and tBu3SiPM2 in tetrahydrofuran at ambient temperature.

Graphical abstract: A novel type of phosphide: synthesis and X-ray crystal structure analysis of (tBu3Si)3P4Li3

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Article information

DOI
https://doi.org/10.1039/B210984K
Article type
Communication
Submitted
07 Nov 2002
Accepted
18 Feb 2003
First published
21 Mar 2003

Chem. Commun., 2003, 990-991

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A novel type of phosphide: synthesis and X-ray crystal structure analysis of (tBu3Si)3P4Li3

H. Lerner, M. Wagner and M. Bolte, Chem. Commun., 2003, 990 DOI: 10.1039/B210984K

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