Issue 5, 2003
From the journal:

Chemical Communications

A novel reaction of dimethylsulfonium methylide with Michael acceptors: application to the synthesis of difficultly accessible vinylsilanes and styrenes†

Sunil K. Ghosh,*a   Rekha Singha  and  Sonali M. Datea  

* Corresponding authors

a Bio-Organic Division, Bhabha Atomic Research Centre, Trombay, Mumbai, India
E-mail: ghsunil@magnum.barc.ernet.in

Abstract

Rather than the usual cyclopropanation and Peterson-type olefination, conditions for a novel elimination reaction from the adduct of dimethylsulfonium methylide and 2-silylalkylidene/arylidene malonate/cyanoacetate/phosphonoacetate leading to geminally substituted vinyl silanes or styrenes, respectively, have been established.

Graphical abstract: A novel reaction of dimethylsulfonium methylide with Michael acceptors: application to the synthesis of difficultly accessible vinyl silanes and styrenes

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Article information

DOI
https://doi.org/10.1039/B211279E
Article type
Communication
Submitted
20 Nov 2002
Accepted
24 Jan 2003
First published
07 Feb 2003

Chem. Commun., 2003, 636-637

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A novel reaction of dimethylsulfonium methylide with Michael acceptors: application to the synthesis of difficultly accessible vinyl silanes and styrenes

S. K. Ghosh, R. Singh and S. M. Date, Chem. Commun., 2003, 636 DOI: 10.1039/B211279E

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